Beselare Posted 9 October , 2012 Share Posted 9 October , 2012 In the book The Master of Belhaven, on page 155 Hamilton makes reference to "vile K Shells". The internet only tells me about atomic K shells! Can anyone please help in describing what these were and why he might have described them as 'vile'? Many thanks Bob Link to comment Share on other sites More sharing options...
centurion Posted 9 October , 2012 Share Posted 9 October , 2012 K rounds were armour piercing bullets fired by rifles and machine guns, initially as an anti sniper shield measure but latterly as an anti tank round. Edit However I suspect that he is referring to shells filled with K-Stoff an asphyxiating gas Link to comment Share on other sites More sharing options...
pjjobson Posted 9 October , 2012 Share Posted 9 October , 2012 Centurion I agree in an artillery context he was most probably referring to K-Stoff shells, or he could have been refering to shells containing Stannic Chloride, referred to in British publications as KJ Shells. Phil Link to comment Share on other sites More sharing options...
centurion Posted 9 October , 2012 Share Posted 9 October , 2012 K-Stoff was Methyl chloroformate (methyl chlorocarbonate) possibly the same as or related to Sannic Chloride? Link to comment Share on other sites More sharing options...
Beselare Posted 10 October , 2012 Author Share Posted 10 October , 2012 Thanks to Centurion and Phil. No wonder he referred to them as 'vile'. Do you happen to know the physical effect of this gas? Bob Link to comment Share on other sites More sharing options...
Thunderbox Posted 10 October , 2012 Share Posted 10 October , 2012 IIRC K-Stoff released phosgene in reaction to atmospheric water vapour. Phosgene is a "non-persistent" "choking agent" in the classification of chemical weapons. It acts by blocking oxygen transfer in the lungs, thus causing symptoms of suffocation. Link to comment Share on other sites More sharing options...
Thunderbox Posted 10 October , 2012 Share Posted 10 October , 2012 IIRC K-Stoff released phosgene in reaction to atmospheric water vapour. Phosgene is a "non-persistent" "choking agent" in the classification of chemical weapons. It acts by blocking oxygen transfer in the lungs, thus causing symptoms of suffocation. Link to comment Share on other sites More sharing options...
centurion Posted 10 October , 2012 Share Posted 10 October , 2012 IIRC K-Stoff released phosgene in reaction to atmospheric water vapour. Phosgene is a "non-persistent" "choking agent" in the classification of chemical weapons. It acts by blocking oxygen transfer in the lungs, thus causing symptoms of suffocation. Vividly described by Wilfred Owen in "Dulce et Decorum" Link to comment Share on other sites More sharing options...
dman Posted 13 October , 2012 Share Posted 13 October , 2012 KJ was designation for stannic (tin iv) chloride, SnCl4. It is a smoke producing agent - when released in the atmosphere reacts with moisture forming tin oxides/hydoxides and hydrocloric acid which gives it a irritant property. Was loaded into artillery shells, mortar bombs and grenades.as a smoke producing agent Often used in conjuction with other chemical agents, both lethal and non lethal (harassing) to "weight" the chemical cloud to prevent from dispersing or evaporating too quickly Another thing was that german gas masks did not filter it out so could penetrate the mask and cause irritation to eyes and respiratory system forcing user to pull mask off Tin is scare and expensive so substitutes in form of silicon tetrachloride or titanium tetrachloride were used as replacements Link to comment Share on other sites More sharing options...
centurion Posted 13 October , 2012 Share Posted 13 October , 2012 Tin was especially scarce in Germany which pre war had been an importer. From the description above I get the impression that KJ shells would be an Allied weapon whilst K shells would be German. Nasty stuff either way. Link to comment Share on other sites More sharing options...
dman Posted 14 October , 2012 Share Posted 14 October , 2012 KJ was an Allied (British) chemical agent If can see if can find copy of "CHEMICALS IN WAR" ny Lt Col (later Brig Gen) A M Prentiss of US Army Chemical Corps published in 1937 Gives in detail all the Chemical agents of WWI and their usage College library might have copy Link to comment Share on other sites More sharing options...
Robert Dunlop Posted 14 October , 2012 Share Posted 14 October , 2012 IIRC K-Stoff released phosgene in reaction to atmospheric water vapour. Phosgene is a "non-persistent" "choking agent" in the classification of chemical weapons. It acts by blocking oxygen transfer in the lungs, thus causing symptoms of suffocation.Phosgene is described as a 'suffocating' agent but I don't think K-Stoff worked this way. Chlormethyl-chloroformate worked as a tearing agent, making it very hard for gunners to see. There is one reference to K-Stoff turning into phosgene but I am not sure how accurate this reference is.Robert Link to comment Share on other sites More sharing options...
centurion Posted 15 October , 2012 Share Posted 15 October , 2012 There is a definition of the various stoffs and K stoff (Methyl chloroformate) is defined as a suffocating agent. Link to comment Share on other sites More sharing options...
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